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Could somebody explain the details, since I find conflicting
information on this question?
Apparently, the alkalis (OH) found in Portland cement
concrete can attack certain materials.
A.) This
website states: (http://www.listentech.com/shop/product/direct-burial-cable/)
The insulation of the cable is
resistant to attack from strong alkalis present in concrete unlike standard PVC
insulated wire to prevent loop failure due to corrosion of the copper core.
B.) Similarily:
(http://www.ampetronic.com/Products/Other-Products/Installation-Accessories/Direct-Burial-Cables/DBC)
PVC cable can not be used for
burial in concrete as the corrosive effects of alkalis present in cement based
compounds will lead to failure of the loop over time
C.) On the
other hand: (http://www.concreteconstruction.net/concrete-articles/will-pvc-react-chemically-with-concrete.aspx)
According to Bernard Erlin, the
principal chemicals in concrete that could conceivably attack plastics are
calcium hydroxide, sodium hydroxide and potassium hydroxide (all the hydroxide
are alkalis, OH). Erlin cites a table from Handbook of Chemistry and Physics
stating that rigid PVC has excellent resistance to strong alkalis. Reference: Bernard Erlin, "Embedded
Metals and Materials Other Than Reinforcing Steel," Significance of Tests
and Properties of Concrete and Concrete-Making Materials, STP 169C, ASTM, West Conshohocken, Pa.,
1994, p. 179.
I have read that Polyethylene insulation (= PE, same stuff
milk cartons are made from) holds up well in concrete, but most wires at the
HomeDepot or Lowes are THHN, which is usually PVC with an additional outer
layer of nylon. What happens if one
would use a regular THHN wire as tracer wire directly buried into a concrete
slap, running alongside the PEX tubing? Do
alkalis diffuse through the PVC insulation jacket and attack the copper itself?
Basically, what is the real corrosion mechanism
of PVC-insulated copper wire directly buried in concrete, if indeed there is one?
Let me know in case you can shed some light on this.
Regards,
Max Osterhasi
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