1. Unions are a good idea with the heatex, but of all the possible system components, they are on the lower end of the failure scale IMO. So if you don't use them, you probably won't ever have need to kick yourself for not doing so
IT probably wouldn't be that much of a kick anyway as it sounds like you can do your own work...
2. Your air separator should have a threaded port on it to allow the air to escape. That will have to be capped to allow an air pressure test.
3. That should work to get the sensor stem into the flow. Electric contact thermal sensors can also work pretty well attached to the outside of copper pipe using heat sync compound and then covering/insulating the sensor from outside air. This is better near fittings where flow turbulence will keep the wall temp closer to average fluid temp at that point. I have seen electric test sensors put in place with no more than heat sync compound and a piece of foam tube pipe insulation to hold them in place.
4. What is the volume of your system? If you know the system volume, then adding the correct ammount of Propolene Glycol to the Axiom to be injected. Then it should be as simple as draining out that same ammount of water and allowing the Axiom to makup for that lost water with PG. This should work as long as the drain point isn't immediately downstream from the Axiom. An isolation valve between the Axiom feed point and the drain point would be ideal as this would force the injected glycol into the rest of the system as the water is drained off. This would also be great for charging/purging the system of air to promote flow thru the entire system.
I don't see why the Axiom wouldn't be able to fill the system. It is basically just a 24V RV or AG sprayer diaphram pump in a fancy package. An inexpensive sump pump with a garden hose fitting in a barrel with the garden hose fitting connected to a drain valve/port should also do it. A washing machine hose should work well for this. Again an isolation valve between the fill point and the drain point would be great. Then as you get close to the complete fill you can run a hose back into the feed bucket(or Axiom) from the drain port. The fluid will recirc into the bucket and any air bubbles will be allowed to escape in the bucket as the water circulates...
Good Luck
OH, and this appears to be an older forum engine, so I think depending on what browser you are using to access the forum, sometimes it reverts to using HTML formatting. In HTML a break or return is accomplished by typing < BR > but as one word, with no spaces between the greater/less than symbols and the BR. I can't type it that way as the forum engine reads it as a break and in the submitted posted text it disappears and it puts a return/break in my sentence:) Using that combination of characters will allow you to break up your single big block into paragraphs...