Sloping away is not a bad thing. If anything gets past the lower trim(also angled) it will at least be inclined to run back out.
I think if I was doing this however, I would stand the lower sill board on edge on a table saw and setting the desired angle rip the bevel before fitting the sill board to the wall. Once setup, I could probably prep enough lower sill for every opening in the house in the ammount of time he took to grind just one
Since the boards/bucks are fit into the ICF once it is stacked, this method would also work well with wood buck material.
What blocks and bucks are you planning?