To add a little more detail.....
My company has used Hydrotech for many years with good results. We are also evaluating Hycrete, a waterproofing addmixture, for some projects, largely because of its Cradle to Cradle credentials.
The problem with addmixture products is, of course cracks. Unless you are 1000% positive that your slab is and will continue be crack free for the life of the project, you need a redundant membrane. Roots can be very invasive and destructive, so a robust root barrier is needed in any vegetated roof.
Hycrete advises that using their addmixture along with a less robust membrane to deal with cracks is usually cost neutral compared to a robust roofing system. This may be OK for a normal roof, but I am very concerned about the "less robust membrane" with roots, even with a root barrier.
I hope to do something like this on our future home, but based on what I know today, I will go with a robust roof membrane below the roof insulation and a robust root barrier system. Providing some positive slope to the membrane to prevent ponding is advisable in any case. With roofing, the devil is in the details of penetrations and edge conditions.
If you have a flat roof with a parapet, make certain that you have overflow drains or scuppers to eliminate the possibility of a structural failure if your roof drains get clogged.
I would appreciate it if you would keep us advised of the details of your project.
Bruce