I almost never advocate for non-barrier pipe in heating systems, if for no other reason because you rarely know if the system will truly never need glycol or a ferrous heat source. circumstances and technology change. oxygen barrier pipe ensures you are always prepared.
Also, you probably don't want to be working with 3/4" on a main floor heating system. nasty stuff... too big. that would be a very unpleasant install if you have to do anything in a joist bay. if you were doing a thin pour, the pour would need to be a bit thicker (1-3/4" to 2" thick min) and you'd have to work hard to get the on center tight enough (typically 9" is the max on center in that app).
probably, almost, a definite could be no. hope that helps

if you want to share more details (size/type of the building, your location, expected heat source, and how you plan to install the tubing on the main floor) i or others might be a little more clear..