One would need much more info to sort out whether the existing boiler will be adequate to supply the barn and if the hydronic fluid supply/return temp drop between the house/barn will be adequate for what you are trying to accomplish. What is the area of each zone, number of circuits in each zone, circuit spacing, and circuit lengths? What is the calculated or measured heat loss for each zone area (with the downward floor heat loss broken out seperately) at your design outdoor temp and desired indoor temps for each zone?
You also may want to take a look at this to gain a better understanding of what is involved in properly designing a HR system:
Borst Hydronic Radiant Floor Heating Design Software