I would replace the A coil only if the fan motor has been replace already , if it hasnt at that age it might not be to far off . At which point you have pretty much a new unit with out the upgrade .
The only plus of solar over your current set up is the tax credit , which from my readings repairs/ partial system upgrades likely would not quilify .
Circulator / and tempering valves are pretty simple . But Im going to defer on that one upgrade desuperheater
Can't comment on the hot tub with out more info ( size / hot water production)