For the inside framed walls that will be against the exterior walls, frame them with 2x4 while laying flat on the concrete, then attach 1/2" or thicker foil faced polyiso insulation to the studs. Tape or caulk seams to form air barrier. Stand up walls, brace, and secure to floor with anchor bolts or tapcons. Now do essentially the same for the wall facing open spaces, but you can put the outer foam sheathing on after the walls are up. Again, tape or caulk seams to block airflow. Caulk bottom plate to concrete floor to air seal as well. For the ceiling I would use engineered I joists suitable for the span and loads you will have. Will you be using the ceiling over this area for storage? If so, factor that in to your joist spans (most span tables for these I joists assume a 10 lb/sq ft dead load (stuff permanently attached to the joists like sheetrock, flooring, insulation, etc.) and 40 lb/sq ft live load (stuff not attached to the floor like people, furniture, boxes of stuff, etc.). A 30' span will most likely require a mid span support beam unless you go with really deep I joists. If you split the span in half, you can easily go with the smaller (and less expensive) 9-1/2" I joists @ 16" on center. The mid span beam could be level with the top/bottom of the joists if you use shorter I joists (also easier to handle) and set them in metal joist hangers attached to the beam. You would likely need one or two posts to support this beam.
I joist information For primary insulation in the walls, I would have wet sprayed cellulose applied since it gives you the most R per $ and is also fire retardant. For the ceiling I would have loose fill cellulose blown in between the I joists to fill them up because it is easily the most R per $. Prior to the application of loose blown ceiling insulation, you would need to have either sheetrock or plywood on the underside of the joists to support the insulation. Insure seams are taped and/or caulked for air sealing. After the ceiling insulation is blown in, you can apply plywood or OSB decking on top for storage space above this room.