The foam goes on the outside of the cargo can. Use 3lb density polyruethane with a mop-on/spray-on UV-protective coating to keep it from breaking down in sunlight. This is a standard method of insulating & rain-sealing flat roofs, but works fine on walls too. The UV protective paints need to be re-applied every 5-10 years.
Steel is gas-tight- only less-than tight seams or weatherstripping would let any of the foam-gases indoors.
There is effectively zero thermal performance to be gained from ceramic paints (NONE!), protestations of some manufacturers notwithstanding. It's a new form of "magic mouse milk, cures what ails ya, WAY better than standard snake oil" kind of marketing.
http://www.greenbuildingadvisor.com/blogs/dept/musings/insulating-paint-merchants-dupe-gullible-homeowners http://www.greenbuildingadvisor.com/blogs/dept/musings/insulating-paint-salesman-tripped-his-own-product There are some finishes with measureable benefits, but they're not about ceramic nanospheres, but rather their raw emissivity & solar spectrum reflectance. CRRC rated "cool roof" finishes have a thermal benefit during the cooling season, but a heating energy cost during the heating season- best used only in cooling dominated US climate zones 1 & 2.
See:
http://coolroofs.org/