A couple of comments regarding insulation choices:
XPS is blown with a mixture of HFCs, the predominant component of which is HFC134a, which has a global warming potential (GWP) of about 1400x CO2. The same polymer as EPS is blown with pentane, at about 7x CO2 GWP, and has a better closed cell structure. The higher R/inch of XPS is due to the blowing agent, but as that agent leaks out over time it's thermal performance falls to that of EPS of the same density. The decay in thermal performance is logarithmic, and the R5/inch labeled performance is something like the average performance over the first 20 years. After 50 years it's pretty much the same as EPS. In Europe XPS is blown with CO2 (GWP= 1x CO2) and at 1.5lbs density has an R-value of R4.2/inch, just like 1.5lb density EPS, and like EPS, has a stable R-value over decades.
Almost all closed cell foam is blown with HFC245fa at about 1000x CO2 GWP. Like XPS the blowing agent leaks out over time (though I don't know the time constants). It's likely that the fully-depleted R-value of 2lb polyurethane is about R5/inch, which is about the performance of 2lb density WATER blown polyurethane (eg Icynene
MD-R-200 or
MD-R-210).
Where ever it's possible to design out XPS or HFC-blown closed cell polyurethane, it's going to be considerably greener. Note that the water-blown Icycene is higher permeance than most HFC-blown 2lb foams, and EPS at any given density is 2.5-3x more permeable than XPS, but in your climate and stackups this is not a problem- if anything it is a benefit.
At only R10, the foundation stackup just barely meets IRC 2012 code-minimums for climate zone 4, and with foam on the exterior of the assembly there is a discontinuity with the slab foam forming a thermal bridge to the cooler-than-optimal subsoil. A bottom-of-the-line 2" + 2" ICF would be better (R16, with an R8 of EPS between the slab and wall.) Alternatively, 3" of interior side EPS, or 1" of EPS + a non-structural studwall insulated with rock wool will get you do reasonable performance.
On the roofing stackup, 1" of vent space isn't usually enough (though it meets code minimums), but if you're applying a 2lb density foam to the underside, that is more protective of the roof deck than a mere 1" of vent would be. Faith-based cold roofs need at least 2" of gap to be as protective as 2" of closed cell foam applied to the underside of the roof, unless you've got a real lightning-splitter of a roof line (say a 16:12 pitch.)
HFC blown goods at R6.5/inch DOES NOT meet
IRC 2012 code minimums for a zone 4 climate- you need R49, and at only 5" you're at less than R35 (best case, using R7/inch polyurethane.) At 3" any 2lb foam will also be adding significant structure. To hit code min more greenly & cheaply, you can get there with
a minimum of R15 of rigid foam above the roof deck (say, 2" of polyiso with 1" of EPS above that, seams staggered for ~R17, with 8-9" of open cell foam or cellulose directly under the roof deck works. Open cell foam would provide at LEAST as good (usually better) air seal as the proposed 5" of ccSPF. Furthermore, rigid foam above the roof deck A: keeps the roof deck average winter temp higher (=warmer), and provides a substantial thermal break on the rafters (that you don't have in your proposed design.) At only 5" of cavity-fill the thermal bridging of the rafters SEVERELY undercuts the performance of high-R/inch foams, since the framing fraction is only good for about R6. At a typical 12% roof framing fraction the "whole-assembly-R" of about R22, and that's including a generous R2 for the thermal performance of the 2x t&g interior. You'd get better performance than that out of 2" polyiso + 2" EPS on the exterior, and leaving the rafter bays empty(!).
At about 17-18 cents per R per square foot, closed cell foam is pretty pricey stuff. Rigid EPS & polyiso run about 10 cents/R-ft
2, open cell foam & XPS about 13 cents/R-ft
2- there's definitely better bang/buck using other methods, independently of the environmental issues.