Posted By cathsand on 24 Sep 2014 08:22 PM
Dana, do you feel that closed cell is simply not a good product, due to the environmental impact? I'm using open cell, but was trying to figure how to easily add to the R value of the roof. Sounds like foam board on the exterior is far better?
At high-R closed cell polyurethane blown with HFC245fa does more lifecycle climate damage than any carbon-reduction it might achieve over the next 50-100 years.
At high-R closed cell polyurethane is also close to being a true vapor barrier, which can create moisture trap issues that need to be considered when designing a stackup. Anything over 2" requires a more detailed analysis of the drying paths.
At lower-R when used for vapor-permeance control, air sealing, or dew point control within an assembly (say, in a studwall flash'n'batt) it can be very useful stuff.
Closed cell foam on the underside of the roof deck limits the drying rate of the roof deck. Insulation on the exterior of the roof deck keeps the roof deck warmer (= dryer), and with a sufficiently high exterior R relative to what insulation you install on the interior such that the average temp at the roof deck is above the typical wintertime dew point average of the interior-space air, you can leave the interior side relatively vapor-open. That ability for the roof deck to dry quickly to the interior makes the assembly more resilient.
Not all rigid foam board is as benign as EPS or polyisocyanurate. All XPS (pink, blue, green board) manufactured in north America is blown with a mixture of agents, the dominant component of which is HFC134a, which has an even
higher global warming potential than HFC245fa (about 1400x CO2 compared to about 1000x. Polyiso & EPS are blown with pentane, at about 7x CO2.)
When using polyiso on the exterior for dew-point control in colder climates (really starting from the cold edge of US climate zone 4 or higher) it's important to de-rate it from it's labeled R-value. The performance of polyiso peaks when the average temperature thorugh the foam is 50-60F, but when the average temp is below freezing it falls off a performance cliff to about half the labeled-R. In climate-zone 4 and lower simply using R5.5/inch (instead of the labeled R6-R6.5/inch) would be good enough. When the average mid-foam temp is going to be lower than 30F, splitting the total foam thickness with a layer of EPS on the exterior would yield higher mid-winter performance, something closer to the labeled R-values, since at foam temps below 30F EPS will have a higher R/inch than polyiso. EPS performance increases fairly linearly with falling temperature, and doesn't have the wild curve to it's thermal conductivity seen with polyiso. The brown line in this graph is polyiso, the black line is EPS.

Note that the crossover between polyiso & high density EPS is at a mid-foam temp of about 7C/45F. The crossover point for Type-I EPS would be below 40F.
Since the dew point of mid-winter conditioned space air is typically 35-40F, you want the average temp at the roof deck to be above 40F. While doing it all in EPS would make the design simpler, the higher performance of the polyiso at even modestly higher temps boosts the seasonal drying rate of the roof deck during the shoulder seasons than it would be with an all EPS solution, or even during warmer mid-winter afternoons, and an all-EPS solution is significantly thicker in zones 5 & higher too.
OK, that's more information than you asked for- I'll try to keep it at the overview-primer level.
See more
here.
Rigid rock wool panels can be used on the exterior as well, but are only available in a limited number of thicknesses/R-values, and have a comparatively low compressive strength- it won't be a walkable roof. For insulating wall sheathing it's pretty good though.