Arkie- That 25F number in the EPS performance rating tables is when the temperature halfway through the foam is +25F. In his climate & stackup it'll run about R4.3/inch,
maybe R4.4/inch, never R4.5 or R5.
Not even the 99th percentile outdoor temperature is as low as 25F in Malalcahuello, Chile, let alone the mid-foam temp at the 99% temp according to the climate tables listed on his page link:
http://en.climate-data.org/location/147654/That wall stackup will be fine in that climate- no need for vapor retarders are required at any layer, but air tightness is important on both the foam layer and the interior layer, to avoid infiltration thermal bypasses.