I'm doing kind of a hybrid system with the screened-in deck I'm building:
PT lumber for the main structure with steel ledger and joist. Call me anal (everyone else does); but since I'll be using composite decking and will be able to see it through that 6' wide glass patio door, I wanted everything to be as straight as possible... and stay that way over time. I did a lot of Yahoo searching on the topic and found some great articles. I don't still have the links to share with you; but they're out there and IMO easy to hunt down. I tried to source some generic galv stuff since the Trex system is rather pricey; but I couldn't find anything local and the price to bring in the small amount I needed killed any savings over the Trex. I will say it's a nice system: multiple anti-corrosion layers with a matte gray/black powder coated final layer. They only come in 1 gauge; which was thicker than I needed for my 10' span. The recommended screws are crazy expensive. I found it a very easy system to work with... I also have a strong metal-working/fabrication background. Even without that, though, anyone decent with tools should be able to do very well with it. I do intend to hook the deck up to a couple of grounding rods. If the price doesn't scare you off, I'd say it's a great option.