Your rebar should always be closer to the tension side...
for walls it is hard to say which face is the tension face - usually the inside due to wind pressure or backfill - but sometimes it can be the outside due to negative wind pressure...
Basement walls - position rebar closer to the inside face
Above Grade walls - dead center because you just don't know...
swimming pool walls - dead center (because water and backfill neutralize each other & you should need no rebar but if the pool is empty then you will likely need a double mat of rebar (because the wall is unrestrained at top)... So place rear everywhere
slabs are trickier.. a good rule of thumb is to place it in the dead center and forget about it... however you might want to have it closer to the bottom in the middle of the room and maybe closer to the top around the perimeter..
but for a free floating slab - just leave it in the center. .