semasse64,
The SIP should be protected with a vapor barrier in a cold climate and a self adhering self sealing bituminous roll roofing underlayment in a warm/wet climate. Then I would use metal furring channels with grooves to snap the pex into. See image below. Here's a website to look at
http://www.libertynrg.com/purlin.htmlThe hollow purlins might be advantageous for letting the roof breath/dry better.
(Panelwright, Thank you for correcting me)