The expansion tank & air-purging work best if you're pumping away from them as opposed to toward them. If the pump is pulling directly from the HX + radiation the head of the loop creates an impedance resulting in higher-frequency pressure fluctuation & cavitation at the bump impellers. If you place the expansion tank & air scrubber near the pump input , the tank behaves as a shock-absorber for that high-frequency impeller "noise", and the air scoop can do it's job, and the pump will run more efficiently. It doesn't matter where in the loop the pump & expansion tank live- it can pump toward the radiation & away from the HX, or toward the HX and away from the radiation, as long as it pumps way from the expansion tank & scoop. On the Navien side loop it might matter- it depends on your water pressure. If your water pressure is under 20psi you may need to pump toward the Navien, since it may lower the pressure on the Navien's HX to below it's operating minimum (~15psi) with the pump running. I don't recall if that's pre-plumbed feature of the 210A with it's own internal pump, but if it is, just assume that they got it right. If there's a power outage, none of it works anyway unless you're running on an emergency backup generator. In that case, simply putting a switch in series with the pump power that you'd flip if your shower ran cold would do it. There are various flow detectors etc. out there that you could use, but if the concern is only for during emergency operation it's hard to rationalize the expense. If the concrete isn't yet poured, a 100' loop of PEX in the slab to pre-heat the cold feed to the Navien makes the system "share" better, without needing extra controls to give priority to the DHW flow.
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