The Kawneer IsoWeb products have good U values for aluminum storefront and windows (~0.35 or so), but I still don't see an IsoWeb entrance door system listed on their site. It would be worth a call to Kawneer to see what they recommend. It seems strange to have a weak link like that in a system that is so much better than typical "thermally broken" US aluminum storefront.
http://www.kawneer.com/kawneer/north_america/en/product.asp?cat_id=1342&prod_id=1840